(Z)-3-Ferrocenyl-2-(3-pyridyl)acrylonitrile
نویسندگان
چکیده
منابع مشابه
(Z)-3-Ferrocenyl-2-(3-pyridyl)acrylonitrile
The mol-ecular structure of the title compound, [Fe(C(5)H(5))(C(13)H(9)N(2))], (I), is analogous to that of the compound (Z)-3-ferrocenyl-2-phenyl-acrylonitrile [Cao & Ye (2008). Acta Cryst. E64, m822], (II), with the pyridine ring in (I) replacing the benzene ring in (II). While the corresponding bond distances and angles in the two compounds show no significant differences, the two dihedral a...
متن کامل(Z)-3-Ferrocenyl-2-phenylacrylonitrile
In the structure of the title compound, [Fe(C(5)H(5))(C(14)H(10)N)], the unsubstituted cyclo-penta-diene (Cp) ring is disordered over two positions, with site-occupancy factors 0.76 (2) and 0.24 (2). The dihedral angles between the substituted Cp ring and the major and the minor components of the disordered ring are 0.9 (5) and 6(2)°, repectively. The plane of the acrylonitrile unit makes dihed...
متن کامل(Z)-3-Ferrocenyl-2-(4-pyridyl)propenenitrile
In the title compound, [Fe(C(5)H(5))(C(13)H(9)N(2))], the pyridine ring makes a dihedral angle of 9.91 (17)° with the substituted cyclo-penta-dienyl ring and the double bond adopts a Z configuration. In the crystal structure, inter-molecular C-H⋯N hydrogen bonds link the molecules into a one-dimensional chain in the a+c direction.
متن کاملMonoclinic form of (Z)-1-ferrocenyl-3-(3-hydroxyanilino)but-2-en-1-one
The title compound, [Fe(C(5)H(5))(C(15)H(14)NO(2))], is a monoclinic polymorph of the previously reported triclinic form [Shi et al. (2006 ▶). Acta Cryst. C62, m407-m410]. The polymorphs feature the same strong intra-molecular N-H⋯O=C hydrogen bonds, but show different packing modes. The mol-ecules in the monoclinic form associate into double chains via O-H⋯O=C and (Cp)C-H⋯O-H inter-actions.
متن کامل2-Ferrocenyl-6-methylpyridin-3-ol
In the title compound, [Fe(C(5)H(5))(C(11)H(10)NO)], the dihedral angle between the pyridyl and substituted cyclo-penta-dienyl rings is 20.4 (3)°. The H atoms of the methyl group are disordered over two positions; their site-occupation factors were fixed at 0.5. The crystal structure is stabilized by well defined inter-molecular O-H⋯N and C-H⋯O hydrogen bonds, leading to the formation of a two-...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808025531